All ace Pokemon of famous Pokemon trainers?

like Cynthia’s Garchomp or Iris’s Axew

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JohtoArcher: HoundoomAriana: none (GSCHGSS) Murkrow (FRLG)Bugsy: ScytherChuck: PoliwrathClair: KingdraEusine: ElectrodeFalkner: PidgeottoJasmine: SteelixJoey: the top percentage RattataLi: HoothootMorty: GengarPetrel: WeezingProton: Golbat (GSC) Weezing (HGSS)Pryce: PiloswineSilver: starterWhitney: MiltankWill: Xatu

HoennAarune: FlygonAnabel: SnorlaxArchie: Sharpedo (SEAS) Kyogre (USM)Brawly: MakuhitaBrendan/May: starterDrake: SalamenceFlannery: TorkoalGlacia: WalreinGreta: UmbreonJuan: KingdraLucy: SeviperMaxie: Camerupt (REOR) Groudon (USM)Matt: none (RSE) Sharpedo (ORAS)Norman: SlakingPhoebe: Dusclops (RSE) Dusknoir (ORAS)Shelley: none (RSE) Sharpedo (ORAS)Sidney: AbsolSpenser: SlakingSteven: MetagrossTabitha: none (RS) Golbat (E) Camerupt (ORAS)Courtney: none (RS) Camerupt (ORAS)Tate and Liza: Solrock and LunatoneTucker: SwampertWallace: MiloticWally: Gardevoir (RSE) Gallade (ORAS)Wattson: Magneton (RSORAS) Manectric (E)Zinnia: Salamence

SinnohAaron: DrapionBarry: starterBertha: Hippowdon (DP) Rhyperior (Pt)Buck: ClaydolByron: BastiodonCandice: Abomasnow (DP) Froslass (Pt)Cheryl: ChanseyCynthia: GarchompCyrus: Weavile (DPPt) Dialga (US) Palkia (UM)Darach: EmpoleonFantina: MismagiusFlint: Infernape (DP) Magmortar (Pt)Gardeina: RoseradeJupiter: SkuntankLucas/Dawn: starterLucian: Bronzong (DP) Gallade (Pt)Marley: ArcanineMars: PuruglyMira: KadabraMaylene: LucarioRiley: LucarioRoark: CranidosSaturn: ToxicroakVolkner: Luxray (DP) Electivire (Pt)

UnovaAlder: VolcaronaBenga: VolcaronaBianca: starterBrycen: BearticBurgh: LeavannyCaitlin: GothitelleCheren: starterChili: PansearCilan: PansageClay: ExcadrillColress: KlinklangCress: PanpourDrayden/Iris: Haxorus (Iris never used Axew in the core series games)Elesa: ZebstrikaGhetsis: Hydreigon (BWBW2) Zekrom (US) Reshiram (UM)Grimsley: BisharpHugh: starterLenora: WatchogMarshal: Mienshao (BW) Conkeldurr (BW2)Marlon: JellicentRosa/Nate: starterRoxie: WhirlipedeShadow Triad: Absol, Banette, AccelgorShauntal: ChandelureSkyla: SwannaZinzolin: Weavile

KalosAliana: DruddigonBryony: BisharpCalem/Serena: starterCelosia: DrapionClemont: HelioliskDexio: none (XY) Alakazam (SMUSM)Diantha: GardevoirDrasna: NoivernEmma: MalamarGrant: Amaura and TyruntLysandre: Gyarados (XY) Xerneas (US) Yveltal (UM)Malva: TalonflameOlympia: MeowsticRamos: GogoatShauna: starterSiebold: BarbarnacleSina: none (XY) Glaceon (MUM)Tierno: CrawdauntTrevor: FlorgesValerie: SylveonViola: VivillonWikstrom: AegislashWulfric: AvaluggXerosic: Malamar

Real lifeMorimoto: Zebstrika (BWBW2) none (SMUSM)Nishino: Snorlax

source: a lot of Bulbapedia pages