Are there any moves that have either 100 accuracy or 100% chance of poisoning the target?

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My life is slop unlucky. I have missed 14 times with toxic in 19 uses. I want a move that can poison for sure.

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Poison Fang: 100 Acc, chance to poison.Cross Poison: 100 Acc, chance to poison.Poison Gas: 85 Acc, poisons.Poison Sting and Poison Jab: 100 Acc, chance to poison.Poison Tail: 100 Acc, chance to poison.Poisonpowder: 75 Acc, chance to poison.Sludge: 100 Acc, chance to poison.

There are more, just look here:http://pokemondb.net/move/all#poison

Besides Toxic Spikes, Toxic is your best bet for poisoning enemies with it’s 90 base accuracy.

Al lthe moves that can poison are:Cross PoisonFling (poison barb)Gunk ShotPoison JabPoison GasPoisonPowderPoison StingPoison TailSecret PowerSludge BombSludgeSludge WaveSmogToxic SpikesTwinneedle.

The moves with a 100% chance are:FlingPoisonPowderToxic Spikes

The moves with 100% chance and accuracy are:Toxic Spikes

Source

Baneful bunkerFlingG-max MalodorMortal spinPsycho shiftToxic spikesToxic threadsourceSynchronize will also poison an opponent that poisons the Pokemon with synchronize.In gen 6 onward, toxic ignores accuracy checks (ie. can’t miss) if used by a poison Pokemon.