Where is the best place to gain Exps. in B2/W2?

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Without counting Pokemon League and Stadions.

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Black TowerVictory RoadCloressStraiton City ex-gym leadersCynthiaNShadow TriadWhite ForestCastelia - Royal UnovaJoin Avenue - the Fitness counter there

Depending at what level you are:

Route 23 - Audino training with Lucky EggNimbasa - Little Court & Big Stadium, once a day and you get a ton of cash + some items too.Plasma frigate (near P2 lab) - Colress, once a day.

Colress at P2 Laboratory with lvl 77-80 Pokemon.In Castelia City with the two game freaks with lvl 74-78 Pokemon. Or the royal unova with lvl 65-68 Pokemon. You need 1000 pokedollars to get on.In nimbasa city with the big and small courts with lvl 60-65 Pokemon.Your rival in Driftveil city with lvl 66-70 Pokemon.Audinos with lucky egg.Black tower.Striaton Gym with two on two battles with cilan, cress, and chili with lvl 65-68 Pokemon.N at victory road with lvl 70-80 Pokemon.Join avenue with the deli person and fitness trainer. Make sure you have a lot of money though.Cynthia at Undella Bay with lvl 74-80 Pokemon.The shadow triad at Iccirus City to to the right of the Pokemon center over the bridges. You will battle all three of them with lvl 74-78 Pokemon.