Who are all the people in Black 2 and White 2 that will trade?

Anyone in the game.

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(Black 2 only) Lass Calla - Route 4- Trades Petilil @ Power Anklet for player’s Cottonee

(White 2 only) Youngster Cotton - Route 4- Trades Cottonee @ Power Weight for player’s Petilil

Hiker Manny - Route 7- Trades Gigalith @ Leppa Berry for player’s Emolga

Roughneck Slick - Humilau City- Trades Tangrowth @ Sitrus Berry for player’s Mantine

Scientist Lillian - Route 15- Trades Rotom @ Max Elixir for player’s Ditto

Lass Diana - Accumula Town- Trades Ambipom @ Sitrus Berry for player’s Excadrill- Trades Alakazam @ Lum Berry for player’s Excadrill

Yancy - Nimbasa CityYancy will accept any of the player’s Pokemon in exchange for the following:- Meowth @ Rare Candy- Wobbuffet @ RageCandyBar- Ralts @ Lava Cookie- Shieldon @ Old Gateau- Rhyhorn @ Rare Candy- West Sea Shellos @ Old Gateau- Mawile @ Lava Cookie- Spiritomb @ Old Gateau- Snorlax @ Rare Candy- Teddiursa @ RageCandyBar- Spinda @ Lava Cookie- Togepi @ RageCandyBar

Curtis - Nimbasa CityCurtis will accept any of the player’s Pokemon in exchange for the following:- Mankey @ Rare Candy- Wobbuffet @ RageCandyBar- Ralts @ Lava Cookie- Cranidos @ Old Gateau- Rhyhorn @ Rare Candy- East Sea Shellos @ Old Gateau- Sableye @ Lava Cookie- Spiritomb @ Old Gateau- Snorlax @ Rare Candy- Phanpy @ RageCandyBar- Spinda @ Lava Cookie- Togepi @ RageCandyBar

In-game trades (Bulbapedia)

Other notes: